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  Freeze and Corrosion Protection for Water-based Heating and Cooling Systems
Page 4

QC-1 Texcool E100 Dowtherm/Dowfrost Closed Loop QC-35 Equivalents

Dowtherm/Frost PG 1 Dowtherm/Frost PG 2 Dowtherm/Frost PG 3 Dowtherm/Frost PG 4 Dowtherm/Frost PG 5

Solutions of DOWTHERM™, or DOWFROST™ fluid can be blended to provide the level of freeze or burst protection your system requires…with freeze protection down to
 -51°C (-60°F) and burst protection below -73°C (-100°F). The table on this page indicates the
concentrations of Dow fluids required to maintain freeze or burst protection at various temperatures.
Freeze Protection Freeze protection is important in systems that must operate all winter, requiring that the fluid remain pumpable and circulating at low temperatures. Freeze protection is also necessary if the system offers inadequate volume for expansion of an ice/slush fluid mixture. Systems required to start up following prolonged winter shutdowns may also be candidates for freeze protection. And the fluid in any system that must be protected in the event of power or pump failure should contain sufficient glycol for freeze protection. Ice storage systems, fire sprinkler
systems, hydronic heating systems, or other systems requiring constant or intermittent winter operation will require freeze protection. The required concentration of glycol to achieve freeze protection is higher than for burst protection and depends on the operating conditions of the
system and the lowest ambient temperature likely to be encountered. For freeze protection, choose a glycol solution concentration that freezes (temperature at which ice crystals start to form) at least 3°C (5°F) colder than the lowest expected exposure temperature.

Volume Percent Glycol Concentration Required
Concentrations of DOWTHERM™, DOWFROST™, and DOWCAL™
Fluids Required to Provide Freeze Protection and Burst
Protection at Various Temperatures

Volume Percent Glycol Concentration Required:

 

For Freeze Protection

For Burst Protection

Temp.,
°C (°F)
DOWTHERM TM,
DOWCAL TM 10
Fluids
DOWFROST TM,
DOWCALTM 20 & N Fluids
 
DOWTHERM TM,
DOWCALTM 10
Fluids 11%
DOWFROST TM,
DOWCALTM 20 &N Fluids
-7     (20) 16% 18% 11% 12%
-12   (10) 25 29 17 20
-18   (0) 33 36 22 24
-23   (-10) 39 42 26 28
-29   (-20) 44 46 30 30
-34   (-30) 48 50 30 33
-40   (-40) 52 54 30 35
-46   (-50) 56 57 30 35
-51   (-60) 60 60 30 35
Note: These figures are examples only and may not be appropriate to your situation. Generally, for an extended margin of protection, you should select a temperature in this table that is at least 3°C (5°F) lower than the expected lowest ambient temperature. Inhibitor levels should be adjusted for solutions of less than 20% glycol. Contact Dow for information on specific cases or further assistance.
 
Burst Protection
Burst protection can be used when a system is inactive during the winter and there is adequate space for expansion of an ice/slush mixture.
When system burst protection is desired, glycol requirements are lower. A concentration capable of maintaining the fluid in an ice/slush mixture is sufficient, provided the volume expansion due to ice crystal formation can be accommodated.
A 30% (by volume) solution of ethylene glycol and a 35% solution of propylene glycol fluid is usually
adequate. This ice/slush mixture is flowable and formation will not cause system damage so long as there is room for expansion. Burst protection is suitable for chilled water systems, lawn sprinkler systems, and other systems that are dormant in the winter.  For proper corrosion protection in HVAC systems operating above
35°C (100°F), a minimum 30% concentration of DOWTHERM ™ SR-1, and DOWFROST ™ fluids is recommended.
DOWTHERM ™ 4000, DOWFROST ™ HD,  DOWFROST TM 20 and DOWTHERM ™ 10 Fluids can be used at concentrations as low as 25% at low temperature. Use of good quality dilution water is critical at low fluid concentrations because some
inhibitor can precipitate out of solution with any impurities present in the water. This loss of inhibitor can reduce the level of corrosion protection, decrease heat transfer efficiency, and
leave piping and other components open to possible corrosion attack.

 

HVAC system freeze / burst /


Corrosion Test Results/Weight Loss in Milligrams (mils penetration per year)
  Water Ethylene
Glycol
DOWTHERM TM SR-1 DOWTHERM TM 4000 DOWCALTM 10
DOWTHERM
TM 10
Propylene
Glycol
DOWFROST TM HD DOWFROST TM
DOWCAL
TM N
DOWCAL TM 20
DOWFROST
TM 20
Copper 2
(0.08)
4
(0.16)
3
(0.12)
2
(0.08)
3
(0.12)
4
(0.16)
1
(0.04)
3
(0.12)
1
(0.04)
Solder 99
(3.14)
1780
(56.5)
4
(0.13)
4
(0.13)
4
(0.13)
1095
(34.7)
2
(0.06)
1
(0.03)
2
(0.06)
Brass
(0.23)
5
(0.46)
11
(0.12)
3
(0.08)
2
(0.12)
3
(0.20)
5
(0.08)
2
(0.16)
4
(0.16)
2
Mild
Steel
212
(9.69)
974
(44.5)
1
(0.04)
1
(0.04)
1
(0.04)
214
(9.80)
1
(0.04)
1
(0.04)
1
(0.04)
Cast
Iron
450
(21.2)
1190
(55.7)
3
 (0.13)
5
(0.23)
3
(0.13)
345
(16.2)
1
(0.05)
3
(0.15)
1
(0.04)
Aluminum 110
(13.2)
165
(19.8)
4
(0.44)
+1
(+0.12)
4
(0.44)
15
(1.80)
+3
(+0.36)
+2
(+0.26)
+3
(0.36)
Samples with a “+” showed weight gain ASTM D1384 – 88°C (190°F) for 2 weeks, 30% by volume glycol, air bubbling

Typical HVAC Applications

Ice Storage For Thermal Energy Storage (TES)
While there are many technologies available for thermal energy storage (TES) systems, ice storage is a
preferred choice for large-scale air conditioning environments. Ice storage systems make and store ice
during non-peak electrical use periods such as overnight or on weekends, then use the stored cold to provide air conditioning during the day when electrical loads and energy costs are at their peak.
Inhibited glycol-based heat transfer fluids — including DOWTHERM TM SR-1, DOWCAL ™ 10, DOWTHERM TM 10, DOWFROST TM HD, and DOWFROST TM 20 Fluids, in particular — are a better choice in TES applications than brine solutions such as calcium chloride because of the severe corrosiveness of salt solutions and resulting system damage.
DOWTHERM ™ SR-1, DOWTHERM ™ 10, and  Inhibited Ethylene Glycol-based Fluids and DOWFROST TM HD, and DOWFROST TM 20 Inhibited Propylene Glycol-based Fluids offer the freeze-point depression capability and low temperature capability necessary to efficiently build ice in TES service. In addition, these Dow fluids contain heavy-duty industrial inhibitor packages that help protect system piping and components against corrosion. The long fluid life and minimal maintenance requirements of these Dow fluids help ensure long-term system reliability, a critical factor in ensuring overall cost and energy savings.
Dow fluids are used in the two most common types of ice storage systems: ice-on-pipe systems and
encapsulated ice systems. Iceon-pipe systems consist of coils of plastic or metal tubing immersed in a tank of water. A chilled solution of glycol and water is circulated through the tubes to build ice on the outer
surfaces during off-peak hours. When air conditioning is needed, the same solution is circulated through the tubes, carrying heat from the building to melt the ice. This chills the glycol based solution which continues to circulate, cooling the building. Encapsulated ice systems operate similarly except the glycol solution is circulated through a tank filled with containers of water. Ice forms in the containers and is later melted by the glycol solution when cooling is needed.
 
Obtaining Excellent Heat Transfer Efficiency If you are weighing the performance of a glycol-based fluid against plain water, you may be concerned about the potential for lost system efficiency with the glycol fluid. However, the fact is, use of a glycol solution in an HVAC system can have relatively little effect
on how well your system performs as long as the fluid type was taken into account during system design or the system was designed to operate with a cushion of excess capacity. In cases where there is no excess capacity, modest system modifications can often compensate for any capacity loss resulting from the
introduction of the glycol fluid into the system. For example, if a glycol fluid is introduced into an air conditioning system formerly operating with plain water, any decline in capacity will probably not be noticed by building occupants as long as the system was designed with excess capacity. If the system is already
nearing its design load, introduction of a glycol-based fluid may aggravate the situation. However, any problems will be noticed only on the hottest days. In cases where increased pressure drop and a resulting decline in the capacity of the system is a problem, a two-step remedy can sometimes be employed. First, flow of solution through the system should be reduced in order to return the pressure drop to its original value. This will have the beneficial side effect of reducing pump horsepower requirements and energy consumption. Next, reduce the chiller operating temperature to lower the fluid temperature into the coil. Reducing the chiller operating temperature compensates for the reduction in fluid flow and returns the coil capacity to its original level. In some cases, shifting the cooling burden from pumps to chiller can actually improve the overall efficiency of the system. Unlike pumps, chillers only use energy in proportion to system load. And, new developments in chillers have led to increased energy efficiency.

Dowtherm/Frost PG 1 Dowtherm/Frost PG 2 Dowtherm/Frost PG 3 Dowtherm/Frost PG 4 Dowtherm/Frost PG 5

QC-1 Texcool E100 Dowtherm/Dowfrost Closed Loop QC-35 Equivalents

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