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Freeze and Corrosion Protection for Water-based Heating and
Cooling Systems
Page 4



Solutions of DOWTHERM™, or
DOWFROST™ fluid
can be blended to provide the level of
freeze or burst protection your system
requires…with freeze protection
down to
-51°C (-60°F) and burst
protection below -73°C (-100°F).
The table on this page indicates the
concentrations of Dow fluids required
to maintain freeze or burst protection
at various temperatures.
Freeze Protection
Freeze protection is important in
systems that must operate all
winter, requiring that the fluid remain
pumpable and circulating at low
temperatures. Freeze protection is
also necessary if the system offers
inadequate volume for expansion of
an ice/slush fluid mixture. Systems
required to start up following
prolonged winter shutdowns may
also be candidates for freeze
protection. And the fluid in any
system that must be protected in
the event of power or pump failure
should contain sufficient glycol for
freeze protection.
Ice storage systems, fire sprinkler
systems, hydronic heating systems,
or other systems requiring constant
or intermittent winter operation will
require freeze protection. The
required concentration of glycol to
achieve freeze protection is higher
than for burst protection and depends
on the operating conditions of the
system and the lowest ambient
temperature likely to be encountered.
For freeze protection, choose a
glycol solution concentration that
freezes (temperature at which ice
crystals start to form) at least 3°C
(5°F) colder than the lowest expected
exposure temperature.
Volume Percent Glycol Concentration Required
Concentrations of DOWTHERM™, DOWFROST™, and DOWCAL™
Fluids Required to Provide Freeze Protection and Burst
Protection at Various Temperatures
Volume Percent Glycol Concentration Required:
| |
For Freeze Protection |
For Burst Protection |
Temp.,
°C (°F) |
DOWTHERM
TM,
DOWCAL TM 10
Fluids |
DOWFROST
TM,
DOWCALTM 20 & N
Fluids
|
DOWTHERM
TM,
DOWCALTM 10
Fluids 11% |
DOWFROST
TM,
DOWCALTM 20 &N
Fluids |
| -7
(20) |
16% |
18% |
11% |
12% |
| -12 (10) |
25 |
29 |
17 |
20 |
| -18 (0) |
33 |
36 |
22 |
24 |
| -23 (-10) |
39 |
42 |
26 |
28 |
| -29 (-20) |
44 |
46 |
30 |
30 |
| -34 (-30) |
48 |
50 |
30 |
33 |
| -40 (-40) |
52 |
54 |
30 |
35 |
| -46 (-50) |
56 |
57 |
30 |
35 |
| -51 (-60) |
60 |
60 |
30 |
35 |
Note: These figures are examples only
and may not be appropriate to your situation.
Generally, for an extended margin of
protection, you should select a temperature in
this table that is at least 3°C (5°F) lower
than the expected lowest ambient temperature.
Inhibitor levels should be adjusted for
solutions of less than 20% glycol. Contact Dow
for information on specific cases or further
assistance.
Burst Protection
Burst protection can be used when a system
is inactive during the winter and there is
adequate space for expansion of an
ice/slush mixture.
When system burst protection is desired,
glycol requirements are lower. A
concentration capable of maintaining the
fluid in an ice/slush mixture is
sufficient, provided the volume expansion
due to ice crystal formation can be
accommodated.
A 30% (by volume) solution of ethylene
glycol and a 35% solution of propylene
glycol fluid is usually
adequate. This ice/slush mixture is
flowable and formation will not cause
system damage so long as there is room for
expansion. Burst protection is suitable
for chilled water systems, lawn sprinkler
systems, and other systems that are
dormant in the winter. For proper
corrosion protection in HVAC systems
operating above
35°C (100°F), a minimum 30% concentration
of DOWTHERM ™ SR-1,
and DOWFROST ™ fluids is recommended.
DOWTHERM ™ 4000, DOWFROST ™ HD, DOWFROST
TM 20 and
DOWTHERM ™ 10 Fluids can be used at
concentrations as low as 25% at low
temperature. Use of good quality dilution
water is critical at low fluid
concentrations because some
inhibitor can precipitate out of solution
with any impurities present in the water.
This loss of inhibitor can reduce the
level of corrosion protection, decrease
heat transfer efficiency, and
leave piping and other components open to
possible corrosion attack. |
 |
Corrosion Test
Results/Weight Loss in Milligrams (mils
penetration per year)
| |
Water |
Ethylene
Glycol |
DOWTHERM TM
SR-1 |
DOWTHERM TM
4000 |
DOWCALTM
10
DOWTHERM TM
10 |
Propylene
Glycol |
DOWFROST TM
HD |
DOWFROST TM
DOWCAL TM
N |
DOWCAL TM
20
DOWFROST TM
20 |
|
Copper |
2
(0.08) |
4
(0.16) |
3
(0.12) |
2
(0.08) |
3
(0.12) |
4
(0.16) |
1
(0.04) |
3
(0.12) |
1
(0.04) |
|
Solder |
99
(3.14) |
1780
(56.5) |
4
(0.13) |
4
(0.13) |
4
(0.13) |
1095
(34.7) |
2
(0.06) |
1
(0.03) |
2
(0.06) |
Brass
(0.23) |
5
(0.46) |
11
(0.12) |
3
(0.08) |
2
(0.12) |
3
(0.20) |
5
(0.08) |
2
(0.16) |
4
(0.16) |
2 |
Mild
Steel |
212
(9.69) |
974
(44.5) |
1
(0.04) |
1
(0.04) |
1
(0.04) |
214
(9.80) |
1
(0.04) |
1
(0.04) |
1
(0.04) |
Cast
Iron |
450
(21.2) |
1190
(55.7) |
3
(0.13) |
5
(0.23) |
3
(0.13) |
345
(16.2) |
1
(0.05) |
3
(0.15) |
1
(0.04) |
|
Aluminum |
110
(13.2) |
165
(19.8) |
4
(0.44) |
+1
(+0.12) |
4
(0.44) |
15
(1.80) |
+3
(+0.36) |
+2
(+0.26) |
+3
(0.36) |
| Samples with a “+” showed weight gain ASTM
D1384 – 88°C (190°F) for 2 weeks, 30% by
volume glycol, air bubbling |
Typical
HVAC Applications
Ice Storage
For Thermal Energy Storage (TES)
While there are many technologies
available for thermal energy storage (TES)
systems, ice storage is a
preferred choice for large-scale air
conditioning environments. Ice storage systems
make and store ice
during non-peak electrical use periods such as
overnight or on weekends, then use the stored
cold to provide air conditioning during the
day when electrical loads and energy costs are
at their peak.
Inhibited glycol-based heat transfer fluids —
including DOWTHERM TM
SR-1, DOWCAL ™ 10,
DOWTHERM TM 10, DOWFROST TM HD,
and DOWFROST TM 20
Fluids, in particular — are a better choice in
TES applications than brine solutions such as
calcium chloride because of the severe
corrosiveness of salt solutions and resulting
system damage.
DOWTHERM ™ SR-1,
DOWTHERM ™ 10, and Inhibited
Ethylene Glycol-based Fluids and DOWFROST
TM HD, and DOWFROST TM 20 Inhibited
Propylene Glycol-based Fluids offer the
freeze-point depression capability and low
temperature capability necessary to
efficiently build ice in TES service. In
addition, these Dow fluids contain heavy-duty
industrial inhibitor packages that help
protect system piping and components against
corrosion. The long fluid life and minimal
maintenance requirements of these Dow fluids
help ensure long-term system reliability, a
critical factor in ensuring overall cost and
energy savings.
Dow fluids are used in the two most common
types of ice storage systems: ice-on-pipe
systems and
encapsulated ice systems. Iceon-pipe systems
consist of coils of plastic or metal tubing
immersed in a tank of water. A chilled
solution of glycol and water is circulated
through the tubes to build ice on the outer
surfaces during off-peak hours. When air
conditioning is needed, the same solution is
circulated through the tubes, carrying heat
from the building to melt the ice. This chills
the glycol based solution which continues to
circulate, cooling the building. Encapsulated
ice systems operate similarly except the
glycol solution is circulated through a tank
filled with containers of water. Ice forms in
the containers and is later melted by the
glycol solution when cooling is needed.
Obtaining Excellent Heat
Transfer Efficiency If you are weighing
the performance of a glycol-based fluid
against plain water, you may be concerned
about the potential for lost system
efficiency with the glycol fluid. However,
the fact is, use of a glycol solution in
an HVAC system can have relatively little
effect
on how well your system performs as long
as the fluid type was taken into account
during system design or the system was
designed to operate with a cushion of
excess capacity. In cases where there is
no excess capacity, modest system
modifications can often compensate for any
capacity loss resulting from the
introduction of the glycol fluid into the
system. For example, if a glycol fluid is
introduced into an air conditioning system
formerly operating with plain water, any
decline in capacity will probably not be
noticed by building occupants as long as
the system was designed with excess
capacity. If the system is already
nearing its design load, introduction of a
glycol-based fluid may aggravate the
situation. However, any problems will be
noticed only on the hottest days. In cases
where increased pressure drop and a
resulting decline in the capacity of the
system is a problem, a two-step remedy can
sometimes be employed. First, flow of
solution through the system should be
reduced in order to return the pressure
drop to its original value. This will have
the beneficial side effect of reducing
pump horsepower requirements and energy
consumption. Next, reduce the chiller
operating temperature to lower the fluid
temperature into the coil. Reducing the
chiller operating temperature compensates
for the reduction in fluid flow and
returns the coil capacity to its original
level. In some cases, shifting the cooling
burden from pumps to chiller can actually
improve the overall efficiency of the
system. Unlike pumps, chillers only use
energy in proportion to system load. And,
new developments in chillers have led to
increased energy efficiency.

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