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DOWTHERM™ • DOWFROST™ Heat Transfer Fluids for HVAC
and Refrigeration Systems Page 5



TES with Dow Fluids
To prevent chiller freeze-ups and permit the manufacture of ice,
fluid solutions used in TES systems must have a sufficiently low
freezing point. To make ice, DOWTHERM ™
SR-1, DOWFROST ™ HD, DOWTHERM ™
10 and DOWFROST™ 20 Fluids are usually chilled to
between -7°C and -3°C (20°F and 26°F). Specifying 25% solutions of
these fluids yields
freezing points below -10°C (14°F) for DOWTHERM ™
SR-1, and DOWTHERM ™ 10 Fluids and -9°C (16°F) for DOWFROST ™ HD
and DOWFROST ™ 20.
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Fluids, providing an adequate margin of safety below the
system’s normal operating temperature to protect against chiller
freeze-up. Since TES systems do not operate above 4°C (40°F), 25%
solutions can typically be safely used without sacrificing corrosion
protection. Note that use of good quality dilution water is especially
critical at low fluid concentrations because impurities in the water
can cause some inhibitor to precipitate out of solution. This
precipitation reduces the level of corrosion protection, decreases
heat transfer efficiency, and leaves piping and other components open
to possible corrosion attack.

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Ground Source Heat Pumps
Ground source heat pump (GSHP) systems are a year-round, energy
efficient heating and cooling solution for applications ranging
from private residences to larger scale public and
commercial buildings. GSHPs are water-based closed loops that
transfer the heat of the earth to a building heat pump in the
winter and transfer the heat of the building to the relative cool
of the earth in summer months. Regardless of the size of the
system, an efficient, high performance heat transfer fluid is an
essential part of any GSHP system. In climates where
temperatures drop below freezing, there is a need for freeze
protection as well as efficient heat transfer. DOWFROST TM,
DOWFROST TM HD, and DOWFROST TM 20 Fluids are leading
choices for GSHP service. Drawbacks of Methanol
Although methanol is sometimes specified for GSHP
service, this fluid has some significant drawbacks. First, with a
flash point of 12°C (54°F), methanol is highly flammable, posing a
danger to installers and to building occupants should a leak
occur. |
Second, due to its
flammability, methanol is classified as a hazardous waste upon
disposal under the U.S. Resource Conservation Recovery Act (and is
subject to similar regulations
in other nations). Third, methanol is characterized as high in
both acute oral and inhalation toxicity, which can pose additional
health and safety risks for building occupants. Regulations in
many areas actually prohibit the use of methanol in underground
systems. Finally, because methanol is often sold as an industrial
commodity it does not normally contain an industrial inhibitor
package to prevent system corrosion.
Advantages of Dow Fluids
In contrast to methanol, DOWFROST ™, DOWFROST ™ HD, DOWCAL™ 20
and DOWFROST ™ 20 Fluids are propylene glycol formulations that
are low in acute oral and inhalation toxicity and have no
measurable flash points because they are mixed in solutions
with water. Both Dow fluids feature industrial inhibitor packages
designed to protect metals commonly used in HVAC systems.
DOWFROST ™ HD and DOWFROST ™ 20
Fluids, in particular, are noted for the additional protection
they provide for copper which is commonly used in GSHP system
tubing and heat exchangers. |
The handling, low toxicity, regulatory, and corrosion protection
advantages of using DOWFROST ™ HD, or DOWFROST ™ 20 Inhibited Propylene
Glycol-based Fluids will normally overcome the slight loss of heat
transfer efficiency. In addition, at concentrations of 25% and under
normal operating temperatures, the heat transfer
efficiency of DOWFROST ™ HD or DOWFROST ™ 20 Fluids compares very
favorably to plain water or methanol. Pumping horsepower requirements
of Dow inhibited glycol-based fluids are similar to, or only slightly
higher than, those of methanol. DOWFROST™ HD and DOWFROST™ 20 Fluids provide
the handling advantages of a propylene glycol fluid, excellent heat
transfer efficiency, long-term system freeze and corrosion protection,
low maintenance operation, lower long term fluid cost, and greater
overall peace of mind at an initial fluid cost usually less than the
overall installed system cost.
Hydronic/Radiant Floor Heating Systems
Long popular in Europe, hydronic (water) heating systems are becoming
an increasingly attractive alternative to forced air systems for
residential heating throughout North America. Hydronic heating systems
consist of a boiler, a pump to circulate the heated water, a water
distribution network, and a series of radiating surfaces located
throughout the home
or embedded in the floor (radiant floor heating). Corrosion protection
is a particularly important consideration when
selecting a heat transfer fluid for a hydronic heating system because
the higher system temperatures can cause rapid degradation of some
glycol fluids. DOWTHERM ™, DOWFROST ™ and DOWCAL ™ Inhibited
Glycol-based Fluids offer industrial strength protection designed for
higher temperature systems to help ensure long service life. In
systems where contact with drinking water is possible, a fluid with
low acute oral toxicity, such as DOWFROST ™ is recommended.
Secondary Grocery Store Refrigeration Loops
Secondary loop refrigeration systems replace the traditional single,
high pressure direct expansion loop with an abbreviated expansion loop
and a larger low-pressure, secondary loop filled with DOWFROST
TM or DOWCAL ™ N Heat
Transfer Fluid, providing even, constant, energy efficient
refrigeration to frozen and chilled food display cases throughout the
store.
Secondary loop refrigeration systems have been shown to reduce
greenhouse gas emissions by reducing the total amount of refrigerant
used. The systems also reduce overall energy consumption for
supermarkets.
Solar Collection Systems
DOWTHERM ™, DOWFROST ™
and DOWCAL ™ Fluids are also used in solar
collection heating systems to
extract solar heat and transfer it to heat buildings or water
supplies. For domestic solar systems, DOWFROST ™
HD and DOWFROST ™
20 Fluids are preferred due to the low acute oral toxicity of
these propylene glycol based fluids.
Other Applications
Dow inhibited glycol-based heat transfer fluids are also widely used
in a variety of other water-based systems, including ice skating
refrigeration systems, fire hydrants, and fire sprinkler systems. In
skating rink systems, for example, sub-freezing temperatures are
maintained by circulating DOWTHERM ™ SR-1,
DOWFROST ™, or DOWTHERM ™ 10 Fluid throughout a network of pipes
embedded in the concrete floor
beneath the ice. In contrast to calcium chloride solutions, which are
often used in these installations, Dow inhibited fluids are inherently
much less corrosive.
The Family of Dow Glycol-based Heat Transfer Fluids
Copyright © The Dow Chemical
Company (1995-2009). All Rights Reserved.
®™* Trademark of The Dow Chemical Company ("Dow") or an
affiliated company of Dow

NOTICE: No freedom from any patent owned by Seller or others is to be
inferred. Because use conditions and applicable laws may differ from
one location to another and may change
with time, Customer is responsible for determining whether products
and the information in this document are appropriate for Customer’s
use and for ensuring that Customer’s workplace and
disposal practices are in compliance with applicable laws and other
governmental enactments. Seller assumes no obligation or liability for
the information in this document.
NO WARRANTIES ARE GIVEN; ALL IMPLIED WARRANTIES OF MERCHANTABILITY OR
FITNESS FOR A PARTICULAR PURPOSE ARE EXPRESSLY EXCLUDED.
†SYLTHERM Heat Transfer Fluids are manufactured
by Dow Corning Corporation and distributed by The Dow Chemical
Company.
Published January 2008
®™Trademark of The Dow Chemical Company (“Dow”) or an affiliated
company of Dow.

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